PhD

Calcium and magnesium are indispensible as secondary nutrients for plant
growth. Availability of these nutrients to plants depends on the form and quantity
present in soil. Soils of the tropics normally pose the problem of acidity due to
high rainfall and leaching of bases causing widespread deficiency of these
nutrients.
The study aims at characterization of soil samples from 23 agro
ecological units of Kerala with respect to supplying power, chemistry, dynamics,
transformations and availability indices of calcium and magnesium and also to
optimize the level of calcium and magnesium for rice nutrition in lateritic soils.
Sixty four representative soil samples from 23 agro ecological units under
five agro ecological zones of the state were collected and characterised for
physico-chemical properties. Among these soils, ninety two per cent were acidic
in reaction, of which sixty three per cent were strongly to very strongly acidic
(4.5-5.5). Lowlands of Kuttanad, Pokkali and Kaipad were extremely to ultra
acidic. Twenty seven per cent of samples were deficient (< 300 mg kg-1) in
available calcium, while sixty seven per cent samples were deficient in available
magnesium (< 120 mg kg-1). Deficiency was negligible in soils from Attapady
hills (AEU 18 and 19), Palakkad central and eastern plains (AEU 22 and 23) and
the lowlands of Kuttanad, Pokkali, and Kaipad (AEU 4, 5 and 7). The availability
of calcium and magnesium increased with pH, cation exchange capacity and
decreased with increase in exchangeable aluminium. Forty one soil samples from
different agro ecological units were subjected to sequential fractionation. The
mean per cent contribution of different fractions to total calcium was in the order
exchangeable > mineral > acid soluble > water soluble > organic complexed,
whereas in the case of magnesium, it was observed as mineral > acid soluble >
exchangeable > water soluble > organic-complexed. Exchangeable calcium and
water soluble magnesium were the sole forms contributing directly to the
available pool.
The quantity-intensity relationship of calcium and magnesium in twenty-
three soils belonging to different AEUs of Kerala were studied at 25oC and 40oC.
Potential buffering capacity or the supplying power of soil had significant positive
correlation with CEC and exchangeable cations in soil. The adsorption data of
both calcium and magnesium at 25oC and 40oC were best explained by Tempkin
adsorption isotherm indicating that the affinity for adsorption decreases linearly
with degree of saturation. The change in free energy of adsorption for calcium
and magnesium was negative in all the soils studied signifying the spontaneous
nature of adsorption. The change in enthalpy (ΔH0) was negative in most of the
soils indicating the process to be exothermic. The close correlation of enthalpy
change with change in entropy proved that as the enthalpy change becomes more
negative, stronger is the bond and more orderly is the adsorption.
The incubation experiment conducted to study the effect of organic matter
on the adsorption of calcium and magnesium revealed a positive influence of
organic matter on availability of calcium and magnesium. The addition of organic
matter improved the supplying power with respect to calcium and magnesium
either through mineralization or formation of stable soluble complexes especially
at higher pH.
Two field experiments to optimize the level of calcium and magnesium
nutrition for rice in low land of north central laterites (Pattambi) revealed the clear
role of calcium and magnesium in improving the yield and yield attributing
characters of the crop. Application of dolomite as per ΔpH was found to be
effective in increasing the yield and maintaining optimum level of calcium as well
as magnesium in soil. Application of lime was not found to influence the in situ
soil pH. The response of crop to magnesium showed yield improvement to the
tune of 1.18 t ha-1 by application of magnesium sulphate @ 120 kg ha-1. Residual
effect of dolomite had significant influence on the yield of rice whereas no
residual effect of applied magnesium sulphate was evident. The correlation
studies and path analysis clearly indicated that plant absorption of calcium mainly
takes place from exchangeable fraction and that of magnesium from water soluble
fraction.