Investigations on high rate anaerobic bioreactor for energy production from rubber latex processing effluent

Abstract

Agro-processing industries often contribute significantly in pollution due to discharge of untreated effluents. By anaerobic digestion of these organic effluents, methane rich gas can be produced which is suitable to generate electricity and process heat. But conventional biogas plants are slow in operation with long hydraulic retention times of 35 to 40 days which necessitates large digester volumes. So, anaerobic digestion of high volume agro-processing effluents is feasible only through high rate bioreactors which can reduce hydraulic retention time to few hours. Rubber latex processing effluent (RLPE) is a dilute waste water for which high rate anaerobic treatment can be an affordable technology. Hence, an investigation was taken up to study the performance of Up-flow Anaerobic Hybrid Bioreactor for energy conversion of rubber latex processing effluent (RLPE). Physico-chemical characteristics of RLPE samples were tested and found that RLPE was a dilute waste water with pH in the acidic range. BOD: COD ratio of 0.44 obtained in this study showed good biodegradability of RLPE. A batch anaerobic digestion study was conducted as a preliminary experiment to investigate the biomethanation characteristics of RLPE. The experiment consisted of four treatments having different composition of RLPE with inoculums replicated thrice. This study could prove that RLPE could be subjected to biomethanation and cow dung slurry can be used as inoculum. Even at a lower inoculum: substrate ratio of 1:2, the system could be started up yielding substantial amount of biogas coupled with good TS reduction. Performance of field scale Up-flow Anaerobic Hybrid Bioreactors (UAHBR) was assessed by operating them at different HRTs of 10, 7, 5, 3 and 2 day. During the study an interruption of 2 months in operation occurred due to shut down of the processing unit due to Covid 19. After interruption of 2 months reactor recovered within one month and it proved that hybrid bioreactor could be restarted easily after a shutdown for few months. Reactor was stable in operation during 10, 7, 5, 3 and 2 day HRTs and exhibited good process efficiency with better pollutant reduction and biogas production. Performance was seen deteriorated beyond 5 day HRT. The bioreactors were operated successively at reduced loading rates corresponding to the longer HRTs after reaching the shortest HRT of 2 day. It was observed that there was no considerable difference in daily biogas production with the earlier values obtained during the progressive decrease in HRT. This revealed that the bioreactors would have achieved the maximum possible microbial population already and there was no further improvement in performance on further passage of time. The performance parameters obtained in the investigations with field scale reactors were used for evolving guidelines to design a full scale anaerobic bioreactor. The UAHBR performance was quite satisfactory at 5 day HRT with respect to pollutant reduction as well as energy production. Hence as criteria, full scale plant was proposed to be operated at 5 day and the corresponding reactor volume was 27 m 3 with 7.2 m 3 gas holder volume. The biogas expected to be produced from the full scale plant can be used in a biogas fired rubber sheet dryer which can save about 500 kg of fire wood per day currently used for drying rubber sheets.